Unassisted Solar Syngas Production by a Molecular Dye-Cobalt Catalyst Assembly in a Tandem Photoelectrochemical Cell
Résumé
The ecological transition requires the development of carbon capture and utilization technologies powered with renewable energies. Direct solar conversion of CO2 in photoelectrochemical cells is a promising approach to produce syngas, en route to fuels and chemicals. We report here on a dyad based on a Ru-based metallorganic dye and a tetraazamacrocyclic cobalt catalyst grafted on NiO to form efficient molecular photocathodes for CO-rich syngas production (ratio CO/H2 > 80:20) from a CO2-saturated aqueous bicarbonate buffer. After integration with a BiVO4/CoPi photoanode in a tandem photoelectrochemical cell in a Z-scheme configuration, syngas could be produced from CO2 water with Faradaic efficiencies of 62% and 14% for CO and H2, respectively under visible light and in the absence of any applied bias, equating to a solar to fuel conversion efficiency of 1.3 10–2 %.
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